ESTUDOS DE CATALISADORES TERNÁRIOS À BASE DE PLATINA, ESTANHO E MOLIBDÊNIO SUPORTADOS EM CARBONO PARA AS REAÇÕES DE OXIDAÇÃO DE METANOL E DE ETANOL
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Data
2012-04-18
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Editor
Universidade Federal do Maranhão
Resumo
The electrocatalytic activities of trimetallic catalysts based on platinum, tin and
molibdenum, dispersed on Vulcan XC-72 carbon using an alcohol reduction method,
were investigated for methanol and etanol oxidation reactions in acid solutions, with
cyclic voltammetry, steady-state polarization curves and chronoamperometry. Among
the catalysts Pt8Sn1Mo1/C, Pt7Sn1,5Mo1,5/C e Pt6Sn2Mo2/C investigated, the best
performance was recorded on Pt6Sn2Mo2/C for the electrooxidation of metanol, as
well as ethanol. In addition, such results when compared with those obtained on Pt/C
sintesized by the same procedure, as well as on Pt/C-ETEK commercial sample,
showed the higher electrocatalytic activity of the Pt6Sn2Mo2/C catalyst.
Descrição
Palavras-chave
Atividade catalítica, Reações de oxidação, Metanol, Etanol, Catalytic activity, Reactions Oxidation, Methanol, Ethanol
Citação
SANTOS JUNIOR, Antonio Fernandes dos. STUDY OF CATALYSTS TERNARY BASED PLATINUM, TIN AND MOLYBDENUM SUPPORTED IN CARBON FOR OXIDATION REACTIONS OF METHANOL AND OF ETHANOL. 2012. 55 f. Dissertação (Mestrado em QUIMICA) - Universidade Federal do Maranhão, São Luís, 2012.