2016-08-192013-01-252012-04-18SANTOS JUNIOR, Antonio Fernandes dos. STUDY OF CATALYSTS TERNARY BASED PLATINUM, TIN AND MOLYBDENUM SUPPORTED IN CARBON FOR OXIDATION REACTIONS OF METHANOL AND OF ETHANOL. 2012. 55 f. Dissertação (Mestrado em QUIMICA) - Universidade Federal do Maranhão, São Luís, 2012.http://tedebc.ufma.br:8080/jspui/handle/tede/943The electrocatalytic activities of trimetallic catalysts based on platinum, tin and molibdenum, dispersed on Vulcan XC-72 carbon using an alcohol reduction method, were investigated for methanol and etanol oxidation reactions in acid solutions, with cyclic voltammetry, steady-state polarization curves and chronoamperometry. Among the catalysts Pt8Sn1Mo1/C, Pt7Sn1,5Mo1,5/C e Pt6Sn2Mo2/C investigated, the best performance was recorded on Pt6Sn2Mo2/C for the electrooxidation of metanol, as well as ethanol. In addition, such results when compared with those obtained on Pt/C sintesized by the same procedure, as well as on Pt/C-ETEK commercial sample, showed the higher electrocatalytic activity of the Pt6Sn2Mo2/C catalyst.application/pdfAcesso AbertoAtividade catalíticaReações de oxidaçãoMetanolEtanolCatalytic activityReactions OxidationMethanolEthanolCNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA::QUIMICA ANALITICAESTUDOS DE CATALISADORES TERNÁRIOS À BASE DE PLATINA, ESTANHO E MOLIBDÊNIO SUPORTADOS EM CARBONO PARA AS REAÇÕES DE OXIDAÇÃO DE METANOL E DE ETANOLSTUDY OF CATALYSTS TERNARY BASED PLATINUM, TIN AND MOLYBDENUM SUPPORTED IN CARBON FOR OXIDATION REACTIONS OF METHANOL AND OF ETHANOLDissertação